Abstract

Au, Pt, and Pt-Au catalysts supported on Al₂O₃ and CeO₂-Al₂O₃ were studied in the oxidation of dichloromethane (DCM, CH₂Cl₂). High DCM oxidation activities and HCl selectivities were seen with all the catalysts. With the addition of Au, remarkably lower light-off temperatures were observed as they were reduced by 70 and 85 degrees with the Al₂O₃-supported and by 35 and 40 degrees with the CeO₂-Al₂O₃-supported catalysts. Excellent HCl selectivities close to 100% were achieved with the Au/Al₂O₃ and Pt-Au/Al₂O₃ catalysts. The addition of ceria on alumina decreased the total acidity of these catalysts, resulting in lower performance. The 100-h stability test showed that the Pt-Au/Al₂O₃ catalyst was active and durable, but the selectivity towards the total oxidation products needs improvement. The results suggest that, with the Au-containing Al₂O₃-supported catalysts, DCM decomposition mainly occurs via direct DCM hydrolysis into formaldehyde and HCl followed by the oxidation of formaldehyde into CO and CO₂.